Abstract
The rheological properties of a moderately concentrated solution of xanthan gum in both the ordered and the disordered state have been studied. Oscillatory shear, steady shear flow, and extensional flow experiments have been performed at different temperatures, covering the order-disorder transition determined by differential scanning calorimetry (DSC). The principle of time/temperature superposition was applied to the xanthan solutions for the different types of flow. Although a master curve covering six decades of frequency could be obtained for the storage modulus over the entire investigated temperature range, less agreement was found for the other modulus. This indicates that the order-disorder transition reflects changes on the molecular scale and slight modification of the physical network structure. To the authors' knowledge, this is the first time that this transition has been observed using these different rheological techniques.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
