Abstract
Experiments concerned with biomimetic synthesis of alkaloids by intramolecular oxidative phenol and nonphenol coupling reactions are described. Preliminary investigations of intramolecular and intermolecular oxidative coupling reactions by iron-DMF and iron-DMSO complexes, and intramolecular oxidative coupling reactions by electrochemical methods followed by biomimetic syntheses of crinine, morphinandienone, and phenanthroquinolizidine alkaloids and a new synthesis of the alkaloid colchicine are presented.
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