Abstract

The fluid catalytic cracking (FCC) process is an alternative olefin production technology, with lower CO2 emission and higher energy-saving. This process is used for olefin production by almost 60% of the global feedstocks. Different parameters including the operating conditions, feedstock properties, and type of catalyst can strongly affect the catalytic activity and product distribution. FCC catalysts contain zeolite as an active component, and a matrix, a binder, and a filler to provide the physical strength of the catalyst. Along with the catalyst properties, the FCC unit’s performance also depends on the operating conditions, including the feed composition, hydrocarbon partial pressure, temperature, residence time, and the catalyst-to-oil ratio (CTO). This paper provides a summary of the light olefins production via the FCC process and reviews the influences of the catalyst composition and operating conditions on the yield of light olefins.

Highlights

  • Olefins, known as alkenes, are critical components in the chemical industry.Light olefins are used to produce many different derivatives used in our daily life, such as packaging, solvents, synthetic fibers, construction, and coatings

  • The type of the feedstock in the fluid catalytic cracking (FCC) unit is related to the crude oil’ source, and the mechanical restriction of the reactor could limit the severity of the operating condition; it is essential to use a proper catalyst to maximize the yield of desired products and enhance the profitability of the unit

  • Xiang-hai et al [91] studied the catalytic pyrolysis of Daqing atmospheric residue (AR) in a confined fluidized-bed reactor using an LCM-5 catalyst, which is a catalyst for the heavy oil contact cracking process

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Summary

Introduction

Known as alkenes, are critical components in the chemical industry. Light olefins are used to produce many different derivatives used in our daily life, such as packaging, solvents, synthetic fibers, construction, and coatings. The processes of catalytic dehydrogenation of light alkanes are another promising technology with high selectivity for olefin production These processes have low capital investment, and they are independent of the oil price; production of hydrogen as a value-added byproduct is another advantage of these processes. The OCM process, with a highly exothermic feature, needs more improvement for catalyst design and development of a reactor suitable for this highly exothermic reaction [6]; this process, with the lowest emission of CO2 energy (CO2 emission resulting from the energy requirement of the process i.e., fuel combustion), suffers from the relatively low ethylene selectivity and high chemical CO2 emission which is produced in the reaction. This review aims to present information about the FCC process for olefin production and provides a summary of different parameters affecting the process, such as the catalyst properties and compositions, and operating parameters, including temperature, residence time, catalyst-to-oil ratio, steam-to-hydrocarbon ratio, and feed properties

Fluid Catalytic Cracking
Catalysts
Zeolite-Based Catalysts
ZSM-5 Additive in FCC Catalysts
ZSM-5 Content
Crystal Size
Temperature
Residence Time
Catalyst-to-Oil Ratio
Steam-to-Hydrocarbon Feed Ratio
Feed Properties
Findings
Concluding Remarks
Full Text
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