Abstract

Carbon-Dots (C-Dots) have drawn much attention in recent years owing to their remarkable properties such as high biocompatibility, low toxicity, nano-scale size, and ease of modification with good tuneable photoluminescence performance. These unique properties have led C-Dots to become a promising platform for bioimaging, metal ion sensing and an antibacterial agent. C-Dots can be prepared using the top-down and bottom-up approaches, in which the latter method is commonly used for large scale and low-cost synthesis. C-Dots can be synthesized using sustainable raw materials or green biomass since it is environmentally friendly, in-expensive and most importantly, promotes the minimization of waste production. However, using biomass waste to produce high-quality C-Dots is still a matter of concern waiting for resolution, and this will be the main focus of this review. Fundamental understanding of C-Dots such as structure analysis, physical and chemical properties of C-Dots, various synthesis methodology and type of raw materials used are also discussed and correlated comprehensively. Additionally, factors affecting the bandgap of the C-Dots and the strategies to overcome these shortcomings are also covered. Moreover, formation mechanism of C-Dots focusing on the hydrothermal method, option and challenges to scale up the C-Dots production are explored. It is expected that the great potential of producing C-Dots from agricultural waste a key benefit in view of their versatility in a wide range of applications.

Highlights

  • Carbon-based nanostructures have extended colossal designation in the field of material science employed by the researchers since it has been reported in 2004 by Xu et al who has accidentally discovered carbon dots (C-Dots) as the new addition to the carbon family when using arc discharge to synthesize single-walled carbon nanotubes (CNTs) (Xu et al, 2004)

  • According to most of the published literature, the quantum yield for prepared C-Dots can usually reach a maximum when the reaction temperature is in the range of 150–200°C, regardless of the different synthesis method such as hydrothermal, thermal decomposition, pyrolysis, microwave irradiation

  • This review highlighted the recent progress in the field of C-Dots focusing on the analysis of structure, composition, synthesis routes, the use of raw materials as a carbon source, strategies to tune optical properties and applications of C-Dots in sensing metal ions, bioimaging and as antibacterial agent

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Summary

A Review on Multifunctional Carbon-Dots Synthesized From Biomass Waste

Nurul Kamilah Khairol Anuar 1, Huey Ling Tan 1*, Ying Pei Lim 1, Mohamad Sufian So’aib 2 and Noor Fitrah Abu Bakar 1. Specialty section: This article was submitted to Bioenergy and Biofuels, a section of the journal Frontiers in Energy Research. Dots Synthesized From Biomass Waste: Design/ Fabrication, Characterization and Applications. Carbon-Dots (C-Dots) have drawn much attention in recent years owing to their remarkable properties such as high biocompatibility, low toxicity, nano-scale size, and ease of modification with good tuneable photoluminescence performance. These unique properties have led C-Dots to become a promising platform for bioimaging, metal ion sensing and an antibacterial agent. C-Dots can be synthesized using sustainable raw materials or green biomass since it is environmentally friendly, in-expensive and most importantly, promotes the minimization of waste production.

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