A Review of Groundwater Arsenic in the Bengal Basin, Bangladesh and India: from Source to Sink

Abstract

The groundwater of the Bengal basin, in Bangladesh and West Bengal state of India, is found to be severely polluted by non-point sourced, geogenic arsenic (As), which has been regarded as the largest public health concern in the human history. The geomorphology and geology of the aquifers play very important role in the three dimensional existence of the As in the groundwater. The provenance of the groundwater As of Bengal basin may be hypothesized to be sourced to the Himalayan orogenic belt, where the contaminant might have originated by deep-seated tectono-magmatism and subsequently introduced to the surficial system by exhumation. Later, sedimentary processes transported the As-laden sediments from the orogenic belt to the peripheral foreland basin of Bengal where, under conducive biogeochemical environment, the As is released from the solid-phase to the circulating groundwater. Ferric hydroxides and pyrite are considered to be the two most important host minerals for As, although clay minerals may also act as important substrates for the sorbed As. The mobilized As then exists in the groundwater until a suitable geochemical sink is available. The mobilization process may be related to reductive-dissolution of metal oxides and hydroxides that exist in the unconsolidated sediments of the Bengal basin. Other mechanisms like pyrite oxidation, redox cycling in surficial soils, and competitive ion exchange are also accepted as potential mechanisms for arsenic mobilization, and multiple processes may simultaneously contribute to the mobilization of As. The processes are significantly complicated by redox disequilibria in the Bengal basin aquifers. These inorganic processes may have been significantly catalyzed and accentuated by microbially mediated activities. The tertiary source of groundwater As is the irrigation return flow from the agricultural fields.