A Reversible Moisture-Responsive Plasmonic Color-Raman and Transmittance Modulation Device by Dispersing Hyaluronan-Functionalized Ag into Nanofibers.

Abstract

Plasmonic physical color generation, which mostly depends on selective absorption, creates unique colors by light transmission and scattering. Based on this, regulating plasmon and transparency with external stimulation is a promising approach for fabricating optical devices with enhanced visual displays; however, few studies have addressed the implementation of dual-optical modulation. In addition, developing a color response to environmental stimuli through the highly shape-sensitive plasmon depth modulation has long remained a significant challenge once the nanostructure is determined. Some stimulations also require high amounts of electricity, which can be costly. In this study, strategically designed hyaluronan-functionalized triangular silver nanoparticles (AgNPs) were embedded in polyvinyl alcohol-polyethylene nanofiber films to achieve a breakthrough in the moisture-responsive dual-optical modulation of the plasmonic color-Raman and transparency. Switchable colors that are reversible were induced in plasmon-resonance-modulation AgNPs via moisture stimulation, adjusting the expansion-tunable dielectric constant of hyaluronan-functionalized AgNPs and varying the electron density due to electron transfer. Furthermore, a moisture gradient was used to decrease the Raman scattering and increase the photoluminescence, which is a significant demonstration of smart-plasmonic evolution. This effect occurred due to the gradual transition from plasmon-driven photoluminescence quenching to photoluminescence enhancement as the interval of the Ag and hyaluronic acid molecules was increased. The transparency of the composite film was also dynamically regulated by turning moisture on/off. This occurred because of the significant difference in hygroscopic expansion between hyaluronan and the nanofibers, which generated a large variation in the total refractive index and caused changes in the surface roughness.