Abstract

Abstract The reactions of the dimethylmetals, Me2 M (M = Zn, Cd), with nitric oxide have been reinvestigated. Two moles of NO are taken up per mole of dimethylmetal in each case. Infrared, laser Raman and mass spectral data indicate that the Me2M. 2NO adducts are best formulated as MeM[O.N(NO)Me] rather than Me2M.M[O.N(NO)Me]2 as had been suggested earlier. On hydrolysis, the methyl(N-methyl-N-nitrosohydroxylamine)metal(II) complexes apparently disproportionate to yield M[O.N(NO)Me]2 and M(OH)2.

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