Abstract
In order to investigate the spatial distribution of 13 C and 18 O of modern carbonate sediments on Great Bahama Bank, ~290 surface samples were collected from a grid of stations approximately 10 km apart between 2001 and 2004. These samples were classifi ed using a modifi ed Dunham scheme, physically separated into six size fractions and subsequently analysed for their mineralogy (aragonite, low-Mg calcite and high-Mg calcite) and 13 C and 18 O values. A striking feature of these data is the relatively positive 13 C values of all the samples. Based on measurements of 13 C and 18 O of the dissolved inorganic carbon and the water, most of the sediments can be considered to be in C and O isotopic equilibrium with the ambient waters. The high 13 C values are suggested to arise from isotopic enrichment of the dissolved inorganic carbon pool by photosynthesis of seagrasses, benthic algae and cyanobacteria on the platform and through the fractionation of HCO 3 − during the precipitation of calcium carbonate. Sediments that are not in C and O isotopic equilibrium are dominated more by skeletal material. The data showed an absence of signifi cant spatial variation in 13 C of the sediments on the Great Bahama Bank and no clear spatial patterns relative to the margin of the platform. The 18 O of the sediment showed more variation, with the interior sediments being isotopically enriched relative to the platform margin. The absence of signifi cant variations in the 13 C in the modern surface sediments of Great Bahama Bank irrespective of facies type suggests that in the case of Great Bahama Bank, downcore variations in 13 C cannot be related to changes in facies.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.