Abstract
A standard enthalpy of formation for perchloryl fluoride of −22.6 ± 1.0 kJ mol -1 was determined from its heat of alkaline hydrolysis which compared with a previously obtained value of −26.5 ± 2.9 kJ mol -1 from the heat of hydrogenation. A convenient calorimeter for gas-liquid reactions is described. The thermochemistry of hydrolysis and bond fission of perchloryl fluoride is discussed in relation to known reactions of the fluoride.
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