Abstract

As a kind of organocatalyst, 1-[4-(perfluorooctyl)phenyl]-3-phenylthiourea was employed to the chemoselective oxidation of sulfides in the presence of 30% H 2O 2. A variety of diaryl, dialkyl, alkyl aryl sulfides could be oxidized to sulfoxide under the mild condition. The catalyst could be easily recovered by fluorous solid-phase extraction for reuse.

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