Abstract

Methylthiomethyl esters of α,β-unsaturated acids 2 were converted into the corresponding ketene acetals 3 by O-silylation. Ketene acetals rearranged in refluxing toluene to give, after methanolysis, the corresponding γ-methylthiomethyl substituted methyl esters 4 . In the case of phenylthiomethylesters the products of α-substitution were observed. Graphic

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