A re-analysis and review of elemental and polycyclic aromatic compound deposition in snow and lake sediments from Canada's Oil Sands Region integrating industrial performance and climatic variables

Abstract

Much of the research from Canada's oil sands region (OSR) shows contaminants of concern (CoCs) throughout the ambient environment surrounding the industrial facilities. While there are some well-established sources of the CoCs, there is also spatial and temporal variability suggesting activity intensity, changes in technology, types and amounts of fuels combusted at the facilities, and climate may affect the results of deposition studies. This study re-analysed published data on the deposition of elements and polycyclic aromatic compounds (PACs) in snow and the sediments of some lakes by incorporating production data from facilities and climate. Using the Elastic Net (EN) regularized regression, variables describing potential associations between facility-specific activity and climate on the deposition of CoCs were identified. Among the selected variables, the combustion of delayed petroleum coke at the Suncor Basemine was associated with the deposition of CoCs, including elements in snow and in some lakes. Similarly, combustion of petroleum coke at Syncrude Mildred Lake was also identified in some models. In both cases, the effects of petroluem coke combustion are likely associated with the emission and deposition of fly ash. The mass of stored petroleum coke was not selected in snow CoC models, but the speed of the wind was a common driver for PACs. However, the mass of stockpiled petcoke was more closely associated with both elements and PACs in lake sediments. While the potential influence of other variables on the occurrence of CoCs in the OSR was also identified, including the production of crude bitumen and synthetic crude, the use of process and natural gases, temperature, and precipitation, these analyses support much of the earlier work and provides additional nuance. While more work is required, these results suggest facility-specific production and climatic data can be coupled with existing approaches to improve the identification of sources of CoCs in Canada's OSR and practices associated with their release.