Abstract
Synthetic applications of exo-glycals, derived from S-glycoside dioxides using the Meyers variant of the Ramberg−Bäcklund rearrangement, are described. These include a formal synthesis of a β-glycosidase inhibitor 12 and an efficient route to spirocyclic glucose derivatives 17 and 18. The synthesis of C-linked disaccharides 24, 31, and 38 and the C-glycosyl amino acid 49 using the Ramberg−Bäcklund rearrangement is also reported. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)
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