Abstract

Some apparent contradictions about the role of O ⨪ 2 in the chain oxidation of sulfites by O 2 are explained. O ⨪ 2 may indeed initiate the chain. On the other hand, if, in the presence of OH scavengers, O ⨪ 2 has a leading part in the chain termination, in the absence of OH scavengers, its role is inhibited by a chain reaction which replaces O ⨪ 2 by OH radicals.

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