Abstract

The rate constant for the oxidation of hydroxycyclohexadienyl radical by ferricyanide has been determined by optical and conductometric pulse radiolysis methods to be 1.8 ± 0.2 × 10 7 M −1sec −1. The reaction is, however, somewhat more complicated than might be expected since spectroscopic studies on the 100 μsec time scale show that ferrocyanide is not the sole immediate reduction product but rather that an intermediate which absorbs in the region of 300 nm is initially produced.

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