Abstract
A new pyrazole derived Schiff base (E)-N'-(2,3-dihydroxybenzylidene)-1-phenyl-5-(thiophen-2-yl)-1H-pyrazole-3-carbohydrazide (W) was devised and synthesized, which exerted a splendid sensitivity and selectivity fluorescence “turn-on” for Al3+, accompanied by a solution color changed to bright green. The complex W[Al3+] could be applied as a sequential sensor to Fe3+. The lowest detection limits of W for detecting Al3+ and Fe3+ ions were 9.42 × 10-9 M and 2.1 × 10-8 M singly. The stoichiometric ratio of W to both Al3+ and Fe3+ was determined to be 1:2 by Job’s Plot, 1H NMR and mass spectrometry titration as well as theoretical arithmetic. Additionally, W was triumphantly applied to detecting Al3+ and Fe3+ in running water.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callMore From: Journal of Photochemistry and Photobiology A: Chemistry
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
