Abstract
Thermolysis of an equilibrium mixture of {1,2-C6H4(SiMe2)(SiH2)}Pt(dmpe) (3; dmpe = 1,2-bis(dimethylphosphino)ethane) and its dimer 4 afforded a novel dinuclear complex consisting of a Pt2Si2 four-membered cycle with formal PtIII centers as well as a small amount of an unexpected dinuclear PtII complex bridged by a cyclodisiloxane ring.
Published Version
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