Abstract
The compound tris(diphenylmethylphosphine)oxo-[1,1':3',1″-terphenyl-2'-olato(2-)-C 2 O]tungsten(IV) toluene solvate contains one cyclometallated 2',6-diphenylphenoxide ligand. A pseudo-octahedral geometry exists for the WO 2 CP 3 core with the terminal oxo and aryloxide O atoms mutually trans. W-O(terminal oxo group)=1.717 (3), W-O(aryloxide)=2.059 (3), W-C=2.151 (5), W-P=2.550 A (average)
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Schedule a callMore From: Acta crystallographica. Section C, Crystal structure communications
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