Abstract

We report experimental results for the photoionization efficiency (PIE) spectrum of Br{sub 2}O along with the ionization energy (derived form the ionization threshold) and the appearance energy (AE) of BrO{sup +} (Br{sub 2}O). A value for the heat of formation of Br{sub 2}O is derived form the AE result. Experiments were performed by employing a discharge flow-photoionization mass spectrometer (DF-PIMS) apparatus coupled to beamline U-11 at the National Synchrotron Light Source (NSLS) at Brookhaven National Laboratory.

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