Abstract
E-mail: kimjn@chonnam.ac.krReceived March 15, 2012, Accepted March 24, 2012An efficient and practical synthesis of MBH adducts of aryl vinyl ketones was developed using DABCO and4-nitrophenol as a proton donor. Addition of a proton donor and the use of excess amounts (3.0 equiv) ofaldehydes were highly beneficial for the yields of MBH adducts of aryl vinyl ketones. Key Words : Morita-Baylis-Hillman adducts, Aryl vinyl ketones, Proton donor, 4-NitrophenolIntroductionThe Morita-Baylis-Hillman (MBH) reaction is one of themost powerful methods of carbon-carbon bond-formation.
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