Abstract

An equation is presented for the potential—time dependence for the reversible re-oxidation of an insoluble product using current reversal chronopotentiometry with an inert electrode. The relationship presented accounts for unequal forward and reverse current densities. Experimental verification is presented with results from a study of silver and lead ions in molten LiCl−KCl eutectic at 710 K using a glassy carbon working electrode.

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