Abstract
A new heterobimetallic potassium magnesiate complex KMg[N(SiMe3)2]2Bn (Bn = PhCH2-) was synthesized by simply mixing magnesium amide and potassium benzyl in toluene. The TMEDA-ligated potassium magnesiate complex was also prepared and its solid structure was characterized by X-ray crystal diffraction, which revealed interactions between potassium and magnesium atoms via amide and benzyl group. The potassium magnesiate complex showed dramatic bimetallic synergistic effect in the catalytic intermolecular hydroamination of styrenes.
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