A pore-scale study for reactive transport processes in double-layer gradient electrode as negative side of a deep eutectic solvent electrolyte-based vanadium-iron redox flow battery

Abstract

Porous electrodes are critical component of redox flow batteries (RFBs), that decide the fluid, species/charge transport and electrochemical reaction properties during the operation of RFBs. It is a potential way to elevate the performance of RFBs by applying the porous electrodes with gradient pore structures. However, it is still lack of a suitable numerical model to understand the reactive transport processes in the heterogeneous pore structures, thus to design and develop the optimal RFB electrodes. Using a lattice Boltzmann model, this work studies the pore-scale reactive transfer behaviors in a double-layer gradient electrode assembling as the negative side of deep eutectic solvents electrolyte-based vanadium-iron RFB, that consists of a graphite felt near the current collector side and a carbon paper near the membrane side. The numerical results reveal the galvanostatic discharging performance of double-layer electrode under the different electrolyte feeding modes and flow rates. Comparing with full flow-through feeding mode, the interdigitated flow feeding mode would give rise to serious inhomogeneity of electrolyte flowing at the low flow rate condition, thereby resulting in the sluggish convective mass transfer performance near the membrane side. Moreover, the total power loss of double-layer electrode is higher than that of the mono-layer carbon paper electrode within the low flow rate range. Conversely, the double-layer electrode with interdigitated flow mode can achieve the lowest total power loss than mono-layer electrodes at the high inlet flow rate. This work provides a new pathway to investigate the RFB power performance effected by the gradient porous structures of electrodes.