Abstract
A nickel(II) co-ordination complex, covalently immobilised on a Merrifield resin, is an effective recyclable heterogeneous catalyst in a room temperature coupling reaction between a Grignard reagent and an organobromide. The immobilised catalyst does not leach metal into solution. Catalyst stability has been rationalised in terms of the combination of hard and soft donor atoms around the variable oxidation state nickel.
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