A Polarization-Sensitive Photodetector with Patterned CH3NH3PbCl3 Film.

Abstract

Perovskite photodetectors with polarization-sensitive properties have gained significant attention due to their potential applications in fields such as imaging and remote sensing. Most perovskite photodetectors concentrate on iodine (I) or bromine (Br)-based materials, primarily due to their straightforward fabrication techniques. The utilization of chloride (Cl)-based perovskites with wider bandgaps, such as CH3NH3PbCl3, is relatively limited. In this work, polarized perovskite photodetectors are prepared by a patterned spatially confined method with polarization sensitivity and excellent optoelectronic properties. The patterned perovskite photodetectors (PP-PDs) not only exhibit outstanding photoelectric conversion performance but also demonstrate polarization sensitivity. PP-PDs showcase remarkable performance, including on/off ratios of 3.4 × 104, an extremely low dark current of 1.56 × 10-11 A, and a rapid response time of microseconds. The responsivity and detectivity of PP-PDs reach 10.6 AW-1 and 3 × 1012 Jones, respectively, positioning them as among the highest-performing MAPbCl3-based photodetectors reported to date. Furthermore, polarization layered imaging sensing is achieved using stepwise scanning of the device. This work provides innovative ideas for realizing high-performance polarized perovskite photodetectors.