Abstract
Reaction of depm (depm = Et2PCH2PEt2) with [Pt2H2(µ-H)(µ-depm)2]+, –90 °C give [Pt2H2(µ-H)(µ-depm)3]+, which decomposes at –70 °C to give the novel Pt(0)–Pt(II) mixed oxidation state complex [Pt2H(µ-depm)3]+ and dihydrogen.
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