A physically-based constitutive model for amorphous glassy polymers in large deformations

Abstract

A physically-based constitutive model for predicting the mechanical response of amorphous glassy polymers at room temperature and low strain rates was established within the frame of thermodynamics and kinematics. In our previous work (Lan et al., 2022b), the concepts of permanent entanglement (PE) and dynamic entanglement (DE) were utilized to reproduce the complicated behavior of amorphous glassy polymers from quasi-static to dynamic loading at temperatures from below to near the glass transition temperature. PE formed by the coiling of macromolecular chains is relatively stable and contributes to the yield and unloading behavior. DE formed by the weak interaction between monomers of adjacent segments is unstable and contributes to the macroscopic yield peak and strain hardening. However, due to including many parameters, the model is not easy to apply in practice. In this work, by ignoring the influence of temperature, the previous model (Lan et al., 2022b) was simplified. Taking polycarbonate (PC) and polystyrene (PS) as examples, the simplified model focused on the macroscopic mechanical behavior under simple compression and cyclic simple compression, analyzed the effects of mesh and specimen size on the evolution of shear bands under plane strain compression, and compared the obvious differences in localized deformation of these two types of amorphous polymers under plane strain compression. In addition, the forging process of PC at room temperature was simulated. By comparing the predictions with the experiments, it is demonstrated that the simplified model can reproduce the macroscopic mechanical response of amorphous polymers under simple compression, cyclic simple compression, plane strain compression and forging.