Abstract
A rigid, covalently linked perylene-3,4:9,10-tetracarboxylic acid bisimide (PBI) cyclophane was synthesized by imidization of a bay-substituted perylene bisanhydride with p-xylylenediamine. The interchromophoric distance of approximately 6.5 Å establishes an ideal rigid cavity for the encapsulation of large aromatic compounds such as perylene and anthracene with binding constants up to 4.6×10(4) M(-1) (in CHCl3 ). For electron-poor guest molecules, the complexation process is accompanied by a significantly increased fluorescence, whereas the emission intensity is dramatically quenched by more electron-rich guests because of the formation of charge-transfer complexes. Furthermore, the influence of the PBI core twist on the binding constant results in a remarkable selectivity towards more flexible aromatic guest molecules.
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