Abstract

Accurate estimation of unsaturated hydraulic conductivity, K(Sw), is crucial for modeling water and solute transport in variably-saturated soils. In this study, a new model for the estimation of K(Sw) based on percolation theory and critical path analysis is presented, in which the pore-throat size distribution is described by the three-parameter Weibull probability density function. To evaluate the performance of the proposed K(Sw) model, two datasets including more than three hundred samples are analyzed. The first dataset includes 240 pore-network simulations, while the second dataset consists of 101 soil samples from the UNSODA database. For the pore-network simulations, for which both pore-throat size distributions and capillary pressure curves are available, we estimate K(Sw) from the capillary pressure curve with RMSLE = 0.54 slightly better than the estimations obtained from the pore-throat size distribution with RMSLE = 0.6. For the soil samples, since only the capillary pressure curve is measured, we estimate K(Sw) from the capillary pressure curve and evaluate three previously proposed approaches for determining the exponent, α, in Poiseuille's law. We find that RMSLE = 0.98 for α = 3, RMSLE = 0.87 for α = 2(4 − D) − (3 − D)/(2D − 3), and RMSLE = 1.06 for α = 4 − 0.74D, in which D is the fractal dimension characterizing the pore space. Comparing the results with previous studies in which the power-law probability density function was used to characterize capillary pressure curve and pore sizes shows that the proposed three-parameter Weibull distribution, in conjunction with the CPA analysis, may more accurately estimate K(Sw) for a wide variety of soils ranging from very fine to very coarse textures.

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