Abstract
AbstractThe quantitative calculation of vapor‐liquid equilibria in mixtures consisting in part of chain molecules requires a partition function valid at both low and high densities. A preliminary partition function for this purpose is described. It is based on the hole theory of liquids and incorporates the concepts of Prigogine and Hijmans for chain molecules. The new partition function is used to represent the vapor‐liquid coexistence curves of long‐chain n‐alkanes.
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Schedule a callMore From: Journal of Polymer Science Part C: Polymer Symposia
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