Abstract

4-Benzoylbenzyl-3-morpholinopropanoate was synthesized, characterized and used as a one-component photoinitiator of Type II. Real-time near-IR spectroscopy was used to study the kinetics of conversion of double bonds of monomers vs. irradiation time. In this initiator, the radicals could be generated through hydrogen abstraction based on intermolecular reaction. Light intensity, concentration of initiator, and the functionality of acrylates affected the polymerization rate and the final monomer conversion.

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