A novel UV-curable waterborne polyurethane-acrylate coating based on green polyol from hydroxyl telechelic natural rubber

Abstract

A novel UV-curable waterborne polyurethane-acrylate (WPUA) was firstly prepared based on hydroxyl telechelic natural rubber (HTNR) via sequential emulsion polymerization. The WPUA was composed of HTNR, Hexamethylene diisocyanate (HDI), 2-hydroxyethyl acrylate (HEA), and the content of hydroxymethyl propionic acid (DMPA) was studied for effects on particle size, stability, and morphology of the new series of WPUA dispersions. The WPUA had a good stability at a total solids content of about 20%. Particle size and dispersion stability slightly decreased with DMPA content. The WPUA gave a good film formation and can provide good wettability with high surface free energy. The mechanical and thermal properties of WPUA film were improved by UV-curing. The effects of photoinitiator (Darocur1173) content were investigated. The UV-cured WPUA films showed better mechanical properties and less water absorption than the not cured WPUA film. Also, the surface wetting was the improvement in the water resistance of the coating on the substrate. In addition, the thermal properties by TGA and the dynamic properties by DMTA slightly increased with photoinitiator dose level due to the higher crosslink density and decreasing the molecular weight between crosslink (Mc) caused the Tg shift to a higher temperature.