Abstract
A novel two-dimensional (2-D) solid material [Ni(en)2]2{SiMoVI8VIV6O42[Ni(en)2]2}·4H2O 1 (en=ethylenediamine) has been hydrothermally synthesized and structurally characterized by IR, UV–Vis spectrum, elemental analysis, XRD, ESR, XPS, X-ray diffraction analysis, magnetic property analysis and electrochemistry study. Single-crystal X-ray analysis reveals that the 2-D framework of compound 1 is based on Mo/V/Si bicapped Keggin clusters interconnected by nickel ethylenediamine complexes. Magnetic susceptibility measurement indicates that compound 1 exhibits antiferromagnetic coupling interactions.
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