Abstract
A new cadmium metal–organic framework (Cd-MOF) has been synthesized by one-pot reaction between 5,5′-(triaz-1-ene-1,3-diyl)diisophthalic acid (H4TEDA) and cadmium acetate. Interestingly, the uncoordinated triazene groups locate in the channel of Cd-MOF. Moreover, the compound exhibits good luminescent property. Benefitting from the porosity, uncoordinated triazene group and luminescence property, Cd-MOF displays high selective response for Hg2+, which makes it as a potential sensor for detecting the toxic metal ions.
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