Abstract
2-Amino- and 2-alkylamino-1,3,5-triazines were smoothly obtained by oxidative (alkyl)amination of 1,3,5-triazine in ammonia-ethanol or alkylamine-ethanol with bis(pyridine)silver(I)permanganate (AgPy2MnO4) as the oxidant. These transformations are the first reactions of 1,3,5-triazine with nucleophiles without ring decomposition and the first examples of nucleophilic substitution of hydrogen on this substrate.
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