Abstract
This study used a solution blending method to coat Ti64 alloy particles with an organopolysilazane (OPSZ) precursor, creating (TiC + Ti3Si)/Ti64 composites via spark plasma sintering (SPS). During SPS, OPSZ decomposes, releasing silicon, carbon, and nitrogen. Nitrogen exits as NH3 and N2, while carbon and silicon partially dissolve in the matrix and partially react with titanium to form TiC and Ti3Si particles. The composite with 0.5 wt% OPSZ exhibited a tensile strength of 1135 MPa and an elongation of 19.0 %, 18.2 % and 28.5 % higher than commercial Ti64 alloy, respectively. The strength increase is attributed to grain refinement, solid solution strengthening, Orowan strengthening, and L phase strengthening. The improved ductility results from fine precipitates promoting dislocation multiplication, the dislocation storage effect of the interface L-phase, and matrix purification by H2 and NH3 from OPSZ decomposition.
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