A novel strategy for harmlessness and reduction of copper smelting slags by alkali disaggregation of fayalite (Fe2SiO4) coupling with acid leaching

Abstract

Copper smelting slags are difficult to achieve harmlessness and reduction because of the presence of abundant of fayalite (Fe2SiO4). This work proposed a novel strategy for harmlessness and reduction of copper smelting slags by alkali disaggregation of Fe2SiO4 coupling with acid leaching. The disaggregation changed the Fe2SiO4 phase by NaOH and released the embedded harmful and valuable metals. The evaluation of disaggregation effect mainly depends on further acid treatment. Especially the total leaching efficiency of As, Zn, Fe, Cu and Pb was achieved 99.7%, 62.5%, 41.5%, 99.9% and 99.1% under diluted HNO3-H2O2 system, respectively. Compared with the non-disaggregated control, the efficiency was accordingly increased by 73.3%, 71.1%, 18.6%, 72.2% and 22.4%. Meanwhile, the content of As, Cu and Pb in the slags decreased from 1165.5 mg/kg, 30085.9 mg/kg and 5008.8 mg/kg to as low as 5.2 mg/kg, 21.2 mg/kg and 15.6 mg/kg, respectively. Interestingly, the strategy brought out 48.1% of the weight reduction of the copper smelting slags. The favorable effect was mainly attributed to the broken of Fe-O-Si bond thereafter improving the acid leaching activation. Therefore, the proposed strategy could potentially be a new method to realize harmlessness and reduction of copper smelting slags.