A novel solar tower simulator for hydrogen regeneration by thermo-catalytic cracking of Ammonia: Energy, Exergy, and CFD investigations

Abstract

This paper presents a novel concept of a central solar tower-based hydrogen regeneration system by thermo-catalytic cracking of ammonia. This includes a closed volumetric receiver for ammonia heating and cracking, a 2.45 kWe high-concentration radiation source, and an air-cooling system for the radiation source. The thermodynamic analysis shows that the net solar-to-hydrogen generation efficiency, first law efficiency, and exergy efficiency are 31 %, 82 %, and 79.8 %, respectively, for the optical efficiency of 35 %, the conversion efficiency of 99 %, and the waste heat recovery fraction of 20 %. The simulations with an ammonia flow rate of 1 kg/hr and flux concentration of 1200 Suns show the regeneration of 1.27 kg H2/day at Jodhpur and 1.57 kg H2/day at Ladakh. Monte Carlo ray tracing simulations revealed that the developed radiation source provides an average flux of ∼ 2 MW/m2 onto a spot size of 20 mm with an efficiency of about 31 %. Reynolds-averaged Navier Stokes-based analyses are used to design a novel air-cooling system for the radiation source. The computations show that (a) an unequal distribution of air mass flow rates at the front mḟ and back mḃ, should be preferred with mḟ>mḃ, and (b) for a total mass flowrate of 0.1 kg/s with mḟmḃ = 4, the maximum surface temperature of reflectors and Xe-arc lamps is less than 315 K and 610 K, respectively. The investigations revealed the feasibility of the concept and provided valuable insight for the planned experimental assessment and scale-up of the solar tower simulator.