A novel scheelite-like structure of BaBi 2Mo 4O 16: Photocatalysis and investigation of the solid solution, BaBi 2Mo 4− xW xO 16 (0.25 ≤ x ≤ 1)

Abstract

A barium bismuth molybdate, BaBi 2Mo 4O 16, was synthesized for the first time. The compound was made by the solid-state technique and studied for photocatalytic degradation of water pollutants. The compound crystallizes in the monoclinic C2/ c system with a = 5.317 (1) Å, b = 12.875 (2) Å, c = 19.390 (3) Å, β = 101.512 (4)°, V = 1327.1 (4) Å 3 and Z = 4. The crystal structure along the a-axis consists of layers of [Bi 2O 2] units and BaO 10 polyhedra both surrounded by isolated MoO 4 tetrahedra representing a scheelite-like structure. Photocatalytic degradation of phenols and substituted phenols, acids and dyes were studied using BaBi 2Mo 4O 16 as catalyst. The catalyst shows selectivity towards chlorine containing aromatics. Substitution of tungsten for molybdenum resulted in retention of structure within the limits 0.25 ≤ x ≤ 1 of the solid solution, BaBi 2Mo 4− x W x O 16. The phases, x = 0.25, 0.50, 0.75 and 1.0, in the solid solution were also used to study the photocatalytic degradation of water pollutants like phenol, substituted phenols and dyes. The photocatalytic activity increases slightly with an increase in substitution of tungsten in the solid solution domain.