Abstract
A novel route for substituted stilbenes 3a-j is developed by cationic cycloaromatization of the corresponding (α-allyl-α-hydroxycinnamyl)-ketene dithioacetal derivatives 2a-j in the presence of ether-boron trifluoride complex. The hydroxydithioacetals 2a-j were obtained by 1,2-addition of allyl or crotyl magnesium bromide with the respective styryl β,β-bis(methylthio)vinyl ketones 1a-j.
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