Abstract

AbstractAn efficient synthesis of novel aryl/heteroaryl‐substituted thieno‐fused heterocycles, that is, thieno[2,3‐b]thiophenes, thieno[2,3‐b]indoles, and pyrazolo[3,2‐c]thiophenes, involving radical‐mediated cyclization of 2‐(2‐bromoheteroaryl)‐3‐methylthio‐3‐aryl/heteroaryl acrylonitriles has been reported.

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