Abstract
A side‐chain liquid crystalline polysiloxane derivative possessing mesogens was synthesized. The mesogens included a large dielectrically‐anisotropic moiety. Phase transition behaviour was investigated and the electrorheological (ER) effect of the polymer considered. No ER effect was observed in non‐sheared polysiloxane derivative because of its high inherent viscosity. However, a large ER effect was observed after pre‐shearing. Pre‐shearing, i.e. shearing with a high shear rate before the measurements, arranges the terminal mesogens in the shearing direction. Furthermore, a dilution of the sample led to a larger ER effect exceeding 10 000 Pa. We thus were able to demonstrate a new approach for the appearance of the ER effect.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.