Abstract
A 1.87-eV energy gap between the lowest energy excitation maximum and the emission maximum in solution was found for the novel hexanuclear gold(I) sulfido complex 1 (Ar=p-CH3C6H4), which has a heterocubane-type structure. Besides this abnormally large Stokes shift of around 15 000 cm−1, 1 exhibits intense orange luminescence in the solid state.
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