A novel phosphorus/nitrogen-containing vinyl imidazolium ionic liquid for improving flame retardancy and mechanical properties of vinyl ester resin, and its carbon fiber composites

Abstract

In daily life, the application of vinyl ester resin (VER) and its carbon fiber composites is limited by their flame retardancy and mechanical properties. In this work, we synthesized an ionic liquid, VIDHP, from diethyl hydroxymethyl phosphate (DHP) and 1-vinylimidazole (VIM). VIDHP can not only cross-links with VER but also enhances the interaction between the resin and the carbon fiber. The flame retardancy and mechanical properties of VER and its carbon fiber composites were effectively improved by the addition of VIDHP. In particular, the addition of 15 wt% VIDHP increased the flexural strength and flexural modulus of the carbon fiber composites by 29.3 % and 42.4 %, while reducing the total heat release and total smoke release by 15.4 % and 18.4 %. The flame retardant mechanism of VIDHP was also investigated. This approach provides a new idea to improve the flame retardant and mechanical properties of VER and its carbon fiber composites.