Abstract

A new novel one-dimensional (1D) polymer involving both tetra- and hexacoordinate mercury(II) complex, [Hg 3(4,4′-bipy) 2(CH 3COO) 2(SCN) 4] n , has been synthesized and characterized. The single-crystal X-ray data of the compound show the complex to be an infinite 1D helical chain, two of the Hg atoms are four-coordinate and one is six-coordinate.

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