Abstract

A flux composed of lithium and rare earth molybdates has been found to be an effective transfer medium for the preparation of yttrium and rare earth iron gallium and aluminum garnets. Magnetic bubble domain properties of epitaxial iron garnet films grown from the molybdate flux are easily controlled by virtue of the transfer process including dimensional control for submicron thick films. The properties of these films compare well to those grown from the PbO·B 2O 3 flux, but the films are contaminant free. This is particularly important for the growth of Nd-doped YAG laser films. Stability region of the garnet phase in the Li 2MoO 4Y 2O 3MoO 3 pseudo-ternary system and solubility are discussed as related to crystal and film growth.

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