A novel nitronyl nitroxide radical and its Gd(III), Tb(III), Dy(III) complexes: Synthesis, structure and magnetic properties

Abstract

Three new lanthanide complexes based on a novel nitronyl nitroxide radical [Ln(hfac)3(NITPhiPr)2] (Ln = Gd(1), Tb(2), Dy(3); hfac = hexafluoroacetylacetonate, NITPhiPr = 4′-isopropyl-phenyl-4,4,5,5-tetramethylimidazoline-1-oxyl-3-oxide) have been successfully synthesized, characterized structurally and magnetically, which all display radical-Ln(III)-radical tri-spin structures. The magnetic studies reveal the ferromagnetic interactions between the Gd(III) ion and radicals and the antiferromagnetic interaction between two radicals in the complex 1. And both Ln(III)–radical ferromagnetic interactions exist in complexes 2 and 3.