Abstract
This paper is the first of two reporting the development of a novel method for describing the transport of chloride ions in concrete under an electrical gradient. In this part, the theory is described and developed. In the second paper, experimental evidence to support the proposed theory is provided. This new theory is designed to correct some deficiencies of the current state of the art. Namely, it considers the effect of concrete being a porous media rather than considering concrete as an aqueous solution as is done with the standard laws; for example, the Nernst–Planck equation.
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