A novel magnetic ion imprinted polymer as a selective magnetic solid phase for separation of trace lead(II) ions from agricultural products, and optimization using a Box–Behnken design

Abstract

In this work, a magnetic ion-imprinted polymer (Fe3O4@SiO2@IIP) as a novel and selective nanosorbent for selective extraction of Pb(II) ions from various agricultural products is presented. The novel lead magnetic ion-imprinted polymer was synthesized by imidazole as a new ligand and grafted onto the surface of Fe3O4@SiO2 NPs. A Box–Behnken (BBD) design was used for optimization of the extraction and elution steps. In the selected conditions, the limit of detection was 0.48ngmL−1, preconcentration factor was 300, the sorption capacity of this new magnetic ion-imprinted polymer was 105mgg−1, and the precision of the method (RSD%) for six replicate measurements was found 3.2%. Finally, the feasibility of the new magnetic ion-imprinted polymer was evaluated by extraction and determination of trace Pb2+ ions in different agricultural products including (orange, mango, apple, kiwi, lettuce, broccoli, carrot, squash, eggplant, radish, mushroom, cucumber, and tomato).