Abstract
AbstractA novel cyan‐bridged macrocyclic nickel complex [{NiL1}{Fe(bipy)(CN)4}]2·5H2O 1 (L1 = 3,10‐dimethyl‐1,3,6,8,10,12‐hexaazacyclotetradecane, bipy = 2,2‐bipyridine) was synthesized and structurally characterized. The complex exhibits one‐dimensional zigzag chain structures. Each ferrous(II) ion connects two nickel(II) ions using two trans CN− groups, and the remaining CN− groups are terminal. Magnetic measurement shows weak ferromagnetic interaction between the nearest Ni(II) ions through the diamagnetic Fe(II) ion.
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